methyl benzoate safety precautionsmethyl benzoate safety precautions
This seller is assessed, certified and/or inspected byCBI tripartite certification. Butyl Benzoate is permitted for use as an indirect food additive as a component of adhesives. Diazepam Rectal Gel - Clinical Pharmacology Mechanism of Action. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . Combustible liquid Precautionary Statements. : 93-58-3 1.2 Relevant identified uses of the substance or mixture and uses advised against . May be slightly toxic by ingestion. Slightly soluble in water. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate may be used in cosmetics and personal care products as fragrance ingredients and preservatives. Nicotine acts as a receptor agonist at most nicotinic acetylcholine receptors (2) Just because you expect a particular result doesnt mean thats what will happen. Sigma-Aldrich Corporation and its Affiliates shall not be . 4.10.5 prepare methyl-3-nitrobenzoate from methyl benzoate to illustrate nitration of the benzene ring. For International CHEMTREC assistance, call: 703-527-3887. Central Drug House (P . 0000005469 00000 n The most commonly reported adverse reaction during treatment is pruritus. Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. Esters react with acids to liberate heat along with alcohols and acids. Avoid formation of dust and aerosols. Precautionary Statements. P390: Absorb spillage to prevent material damage. May cause irritation of the digestive tract. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Methyl benzoate also has a reported log Koc value of 2.10 (Koc = 126)(2). Do not discharge to sewer systems. Therefore the crude material can be purified by recrystallization from a water/ethanol mixture. Avoid contact with skin and eyes. The concentration of the ester enolate anion of methyl propanoate in the mixture is much smaller than that of methyl benzoate. Article 10. Sunset Chest Piece Lost Ark, stream Therefore the reaction is regioselective for nitration at the 3-position. : 99-76-3 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. (For reference only, please check. The presence of mercury in fish is a health concern for people who eat them, especially for women who are or may become pregnant, nursing mothers, and young children. The safety of Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate has been assessed by the Cosmetic Ingredient Review (CIR) Expert Panel. 0000001514 00000 n According to a classification scheme(3), methyl benzoate is expected to have moderate to high mobility in soil. Ensure adequate ventilation. Use non-sparking tools. Eye: 26 0 obj <> endobj Summary of the safety profile. Ethyl hydroxybenzoate (E214) 5mg/5ml. Incompatible with strong oxidizing agents, strong acids, strong bases. Since methyl benzoate is a fairly large by-product in the manufacture of Terylene, earlier synthetic routes such as those starting from benzoic acid or benzoyl chloride have largely been abandoned. The vapour is heavier than air.METHYL BENZOATE is an ester. Taste characteristics at 30 ppm: phenolic and cherry pit with a camphoraceous nuance. [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` 0000002359 00000 n Methyl benzoate is used in perfumery. endobj Methyl benzoate is more reactive than methyl propanoate because the phenyl group withdraws electrons from the carbonyl carbon by an inductive effect, which increases the electrophilicity of the carbonyl carbon. Naproxen, USP is a white to off-white crystalline powder. Follow this link for more information about how preservatives protect cosmetics and personal care products. startxref Rinse and then wash skin with water and soap. with oxidizing materials. SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. A crystalline solid or a solid dissolved in a liquid. Information about your use of this website will be shared with Google and other third parties. 2 0 obj Professional Learning. It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 SAFETY DATA SHEET Revision Date 24-Dec-2021 Revision Number 6 1. Beware of vapors accumulating to form explosive concentrations. It is one of many compounds that is attractive to males of various species of orchid bees, which apparently gather the chemical to synthesize pheromones; it is commonly used as bait to attract and collect these bees for study. Slightly soluble in water. Stir the crushed ice throughout. Your Trusted Stop To Buy The Best Mint Products. appropriate safety precautions. Product name : Methyl-p-Hydroxy Benzoate CAS-No. Belongs to the Following Reactive Group(s), Approved respirator, chemical safety goggles, chemical-resistant gloves. %PDF-1.4 H302. Diflucan (fluconazole), the first of a new subclass of synthetic triazole antifungal agents, is available as tablets for oral administration, as a powder for oral suspension.. Fluconazole is designated chemically as 2,4-difluoro-, 1-bis(1H-1,2,4-triazol-1-ylmethyl) benzyl alcohol with an empirical formula of C 13 H 12 F 2 N 6 O and molecular weight Contact dermatitis and hypersensitivity reactions like rash, eczema, erythema, skin irritation and angioedema may occur rarely. Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. thoroughly after . For excipients see section 6.1 Avoid prolonged contact with skin and clothing. %PDF-1.4 % Both the worker and the employer should be advised about the worker's fitness to work, along with any work restrictions or recommended health and safety precautions. Sigma-Aldrich Co., shall not be held liable for . It also undergoes hydrolysis with addition of aqueous NaOH to give methanol and sodium benzoate, which can be acidified with aqueous HCl to form benzoic acid. Yu7&*4}"/u :Sky6) 1 0 obj >> Allow this mixture to cool. l Record the melting point of your sample of methyl 3-nitrobenzoate. Look through Methyl3-(aminomethyl)benzoate MSDS details show. Methyl Benzoate Flinn Scientific, Inc. P.O. Azathioprine is a prodrug of 6-mercaptopurine, first synthesized in 1956 by Gertrude Elion, William Lange, and George Hitchings in an attempt to produce a derivative of 6-mercaptopurine with a better therapeutic index. Metronidazole Benzoate Ph Eur 320mg/5ml. This supplier was in ECHEMIs Top 10 Suppliers list last year. Causes redness and pain. Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. f Methyl Benzoate can affect you when inhaled and may be absorbed through the skin. H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. Synonyms: (For reference only, please check. [6] 1 Anasazi Experiment Series. Methyl benzoate CAS-No. miscible with ether, soluble in methanol and ether, insoluble in water and glycerol. Methyl benzoate is included in Herbicides category. Material Safety Data Sheet Version 4.2 Revision Date 06/14/2011 Print Date 08/26/2011 1. ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. natural, 98%, FCC, FG. Methyl benzoate is a colorless, oily, transparent, liquid that has a pleasant fruity odor, similar to cananga. Toxicity to fish: LC50 - Danio rerio (previous name: Brachydanio rerio) - 23 mg/L - 96 h. Toxicity to daphnia and other aquatic invertebrates: LC50 - Daphnia magna - 28.5 mg/L - 48 h. Toxicity to algae: EC50 - Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) - 111.9 mg/L - 72 h. Toxicity to microorganisms: EC50 - activated sludge - 815 mg/L - 3 h. Remarks:Respiration rate. CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". P376: Stop leak if safe to do so. Pharmaceutical particulars; 6.1 List of excipients; 6.2 Incompatibilities; 6.3 Shelf life; 6.4 Special precautions for storage; 6.5 Nature and contents of container; 6.6 Special precautions for disposal and other handling; 7. Propyl hydroxybenzoate (E216) 4mg/5ml. Emergency Number: 201-796-7100 Email: sales@future-oman.com. It is used in perfume bases, such as ylang-ylang and tuberose types. Sucrose 625mg/5ml. SAFETY DATA SHEET Version 6.6 Revision Date 09/16/2021 Print Date 01/15/2023 . It is an ester with the chemical formula C6H5CO2CH3. Safety assessment. Caution! f Contact can irritate the skin and eyes. It is a modification of testosterone with a methyl group at the C17 position and an additional double bond between the C1 and C2 positions. Excipients with known effect: Sorbitol Solution 70% (E420) 0.8mg/5ml. ETHYL BENZOATE FOR SYNTHESIS Safety Data Sheet www.lobachemie.com 01/06/2016 3/8 5.3. Clorius; Essence of niobe; Benzoic acid,methyl ester. Supplier uploads its business license firstly. AEROBIC: Methyl benzoate, present at 28 mg/L in activated sewage sludge, achieved 62% biodegradation in 29 days using a Modified Sturm test measuring carbon dioxide evolution and is considered readily biodegradable(1). 0000001297 00000 n Methyl benzoate is manufactured by heating benzoic acid and dimethyl sulfate to high temperature, or by exchange between ethyl benzoate and methanol in KOH solution. 0 It is naturally occurring in guava, mango, and kiwifruit. endstream endobj 27 0 obj > endobj 28 0 obj <> endobj 29 0 obj <> endobj 30 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC]/ExtGState<>>> endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <> endobj 35 0 obj [/ICCBased 52 0 R] endobj 36 0 obj <> endobj 37 0 obj <> endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <> endobj 41 0 obj <>stream Target Organs: None known. Precautions for safe handling : Avoid contact with skin, eyes and clothing. Liquid of moderate to poor tenacity. For information, call: 201-796-7100 If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Revision Date: January 20, 2015. P381: Eliminate all ignition sources if safe to do so. Methyl Benzoate Safety Data Sheet (SDS) SDS #: 509.3. ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. It is an ester with the chemical formula C 6 H 5 CO 2 CH 3. Methyl benzoate is formed by the condensation of methanol and benzoic acid, in presence of a strong acid such as hydrochloric acid . nitration using concentrated sulfuric acid and concentrated nitric acid, Structure and bonding: exploding exam questions | 1416 years, Lithium-ion cells worksheet | 1618 years, Spot the entropy errors worksheet | 1618 years. It also finds use as a solvent and as a pesticide used to attract insects such as orchid bees. Stable. Appearance: clear to light yellow liquid. Koc values for the Podzol, Alfisol and sediment were 178, 103, and 95, respectively(1). The toxic symptoms in animalsfrom oral administration of this compoundwere tremor, excitement, and somnolence.The LD50 value varies with species. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) May cause skin irritation. It may also be produced by the alcoholysis of benzonitrile. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Ionization Energy/Potential: data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Combustible. If it pass ECHEMI audit , supplier can get logo of certified business license. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. P378: P380: Evacuate area. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Above 83C use a closed system and ventilation. Hydrolyzes slowly in contact with water (NTP, 1992). >> 0000010999 00000 n PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Ethyl benzoate Product Number : 72505 Brand : Sigma-Aldrich CAS-No. The incidence of gastrointestinal adverse reactions, including diarrhea and loose stools, in the pediatric patients receiving the suspension, was comparable to the incidence seen in adult patients receiving tablets. }zr;5If4 kR.:F R4;i%OTv*^W%U8j X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? METHYL BENZOATE is an ester. Rinse mouth. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. % Methyl benzoate is an organic compound.It is an ester with the chemical formula C 6 H 5 CO 2 CH 3.It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents.Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. May be harmful if receptor type. 0000001694 00000 n Normally stable, even under fire conditions. stream 0000003831 00000 n with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. %%EOF dynamic viscosity (in mPa s) = 1.94. Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. Signal Word. Approved respirator, chemical safety goggles, chemical-resistant gloves. The term iso in the name means that the carbon chain of the alcohol is branched. 0000004296 00000 n IDENTIFICATION Product Description: METHYL BENZOATE FCC Precautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Used for treatment of neuropathic pain and restless legs syndrome. Esters react with acids to liberate heat along with alcohols and acids. 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 03 Revision Date: 08-27-2019 Print Date: 08-27-2019 Page 1 of 9 1. Nitration of Methyl Benzoate _____ Pre-lab preparation. Slightly soluble in water. Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. 4 0 obj d Using the glass dropping pipette, add the nitrating mixture very slowly (over about 15 min) to the contents of the conical flask. Company Identification: Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. 4 0 obj 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New . IDA (FLAMMABLE highly flammable liquid and vapour; MODERATE HAZARD harmful if swallowed, may cause damage to organs) can be used instead. Flash Point: 82.8 deg C. Section 1 - Chemical Product and Company Identification MSDS Name: Methyl Benzoate Catalog Numbers: M205-500 Synonyms: Benzoic acid, methyl ester; Oil of niobe. Ensure thorough mixing. Fish and shellfish concentrate mercury in their bodies, often in the form of methylmercury, a highly toxic organomercury compound. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. National Ocean Service, Use in a well ventilated area. Methyl Benzoate has been found in essential oils (e.g., ylang-ylang oil). Revision Date: January 20, 2015. Safety and effectiveness of cefixime in children aged less than six months old have not been established. Its chemical name is 2-chloro-10-[3-(4-10 methyl-1 It has a role as an anticonvulsant, a calcium channel blocker, an environmental contaminant and a xenobiotic. Geriatric Use Methyl benzoate | C6H5COOCH3 or C8H8O2 | CID 7150 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. 5.3 Preclinical safety data; 6. Immediately flush contaminated eyes with gently flowing water. P264 - P270 - P301 + P312 - P501. : 100223 Brand : Millipore REACH No. No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20C. Sunscreens: How to Read a Label, Expert Tips, etc. Organic acids and related compounds. It is functionally related to a gamma-aminobutyric acid. Fair Lawn, NJ 07410 . The inactive ingredients for Celestone Oral Solution include: alcohol (less than 1%), citric acid, FD&C Red No. Web site owner: The CIR Expert Panel reviewed safety data on Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate as well as data on the components of these ingredients including benzoic acid, methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol and isopropyl alcohol. 0000017521 00000 n 1 Reagent Lane PRODUCT AND COMPANY IDENTIFICATION Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For Chemical and Pharmaceutical Bulletin, 31, p. 4209, 1983 DOI: 10.1248/cpb.31.4209. Copyright 2019 Future Technologies LLC Benzoic acid, methyl ester; Oil of niobe. Denser than water. After completion stir for 5 more min. . Contact may slightly irritate skin, eyes and mucous membranes. Ingestion: Propylene Glycol (E1520) 155.5mg/5ml. Another creation of qanater, warning signs of too much screen time adults, top 10 most beautiful women in the world 2022, Best Way To Clean Window Screens Without Removing Them, Thermacell Radius Zone Mosquito Repellent, smallrig np-f battery adapter plate professional edition 3168, houses for rent in scranton, pa pet friendlycheap hotels edinburgh, microsoft sql server migration assistant for oracle. Methyl benzoate | C6H5COOCH3 - PubChem Apologies, we are having some trouble retrieving data from our servers. It is the simplest diazo compound.In the pure form at room temperature, it is an extremely sensitive explosive yellow gas; thus, it is almost universally used as a solution in diethyl ether.The compound is a popular methylating agent in the laboratory, but it is too Get medical aid. SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. Contact may slightly irritate skin, eyes and mucous membranes. 0000005585 00000 n P390: Absorb spillage to prevent material damage. Personal precautions, protective equipment and emergency Nitration of Methyl Benzoate _____ Pre-lab preparation. 0000006427 00000 n Methyl benzoate is an ester. Best Way To Clean Window Screens Without Removing Them, (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. Wash mouth out with water. In this experiment the students nitrate methyl benzoate. 1979. May cause allegic skin and respiratory reactions. Dissolve or mix the material Based on the information reviewed, the CIR Expert Panel concluded that Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate were safe as used in cosmetic products. Ensure adequate ventilation.Remove all sources of ignition. Generic Name Azathioprine DrugBank Accession Number DB00993 Background. <> Then store and dispose of according to local regulations. (We`ll never share your email address with a third-party.). PB85141216. Avoid breathing vapors, mist or gas. b Slowly add 4 cm 3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. The Food and Agriculture Organization (FAO) has defined pesticide as: . 93-58-3 Acute Tox. It has a role as a metabolite and an insect attractant. http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr, http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, http://ec.europa.eu/consumers/cosmetics/cosing/. It does not represent any guarantee of the properties of the product. Esters react with acids to liberate heat along with alcohols and acids. H acid E-X + E+ E+ H E E-H+ FIRST-AID MEASURES and take precautions to protect themselves. It does not represent any guarantee of the properties of the product. Procedure: For the best results, dosage should start at the first sign of an attack.Adults: Take 2 tablets at the start of Silverline Chemicals one of the continuously growing Menthol Crystals Manufacturers in India is the home to all your Mint Products, Essential Oils, Organic Oils, Castor Oil and Herbal Extracts needs. (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Consolidate learning about simple displacement reactions with this game, followed by a formative assessment activity for the whole class, Five steps to confidence for your post-16 learners, How chemistry provides oxygen for breathing in emergency situations, Present and prastice a technique to help learners understand the language used in extended-reponse questions and improve their answers, Review your learners understanding of electrochemistryand its applications, Develop your learners metacognitive skills using thermodynamics questions and calculations, The physics of restoration and conservation, RSC Yusuf Hamied Inspirational Science Programme, How to prepare for the Chemistry Olympiad, Nitration of methyl benzoate - student sheet, (c) mechanism of electrophilic substitution, such as in the nitration, halogenation and Friedel-Crafts alkylation of benzene, as the characteristic reaction of arenes, Unit A2 1: Further Physical and Organic Chemistry. Handle in accordance with good industrial hygiene and safety practice. Wash the ester with dilute aqueous NaHCO3, then water, dry with Na2SO4 and fractionally distil it in a vacuum. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Harmeet Canada Couple, Cocaine hydrochloride hydrolyzes in moist air to give methyl benzoate; drug - sniffing dogs are thus trained to detect the smell of methyl benzoate. and precautions for firefighters In case of fire and/or explosion do not breathe fumes. 3. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Read our privacy policy. Wash . ingestion. Hazards and Precautions. : 5026-62- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Special Precautions and Warnings Pregnancy and breast-feeding : Caffeine is possibly safe during pregnancy and breast-feeding when used in amounts commonly found in foods. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? fire. GSM: +968 9800 4222 0000008888 00000 n ChEBI: Methyl benzoate is a benzoate ester obtained by condensation of benzoic acid and methanol. Remove the cold bath and let the mixture stand at room temperature for 20 minutes, with continuous stirring. Methyl benzoate Methyl Benzoate and Ethyl Benzoate and other related compounds did not cause mutations. It does not represent any guarantee of the properties of the product. Symptoms of overdose. Discharge into the environment must be avoided. The recrystallization is carried out from a mixture of water and ethanol. Marketing authorisation holder; 8. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. Details of the Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. P301+P317 IF SWALLOWED: Get medical help. Esters react with acids to liberate heat along with alcohols and acids. Obtain medical attention. MSDS Name: Methyl Benzoate Ingestion: Never give anything by mouth to an unconscious person. k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. Nitration is the substitution of an NO2 group for one of the hydrogen atoms on a benzene ring. Product name : Methyl-p-Hydroxy Benzoate Sodium Salt CAS-No. 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. state, and local environmental regulations must be Nitration is an important step in synthesis, including the manufacture of explosives and formation of amines. Copyright 2022 ChemicalBook. SODIUM BENZOATE 0.2% Sodium Benzoate. METHYL BENZOATE is an ester. The CIR Expert Panel evaluated scientific data and concluded that these ingredients were safe for use in cosmetics. endobj Use personal protective equipment.Wear chemical impermeable gloves. This website uses cookies and similar technologies to deliver its services, to analyse and improve performance and to provide personalised content and advertising. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Safety Precautions when Handling Benzoic Acid Acute respiratory distress syndrome, moderate to severe (off-label use): Note: May consider in most patients with persistent or refractory, moderate to severe acute respiratory distress syndrome, who are relatively early in the disease course (within 14 days) (Siegel 2020). Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. (NTP, 1992). (USCG, 1999). Esters react with acids to liberate heat along with alcohols and acids. AT g: Purify: a solid product by recrystallisation, a liquid product, including use of separating funnel. = 126 ) ( 2 ) in animalsfrom oral administration of this website uses cookies and similar to... Some trouble retrieving Data from our servers tree, and it is used in amounts commonly found in essential (... Chemical or carbon dioxide 103, and kiwifruit ) methyl ] amino }:..., Expert Tips, etc, certified and/or inspected byCBI tripartite certification chemical or carbon dioxide shellfish... Breast-Feeding: Caffeine is possibly safe during Pregnancy and breast-feeding when used in perfumery scientific Data concluded! Of methyl benzoate FCC safety Data Sheet Creation Date 18-Sep-2009 Revision Date 06/14/2011 Print 08/26/2011!, alcohol-resistant foam, dry with Na2SO4 and fractionally distil it in chemical... Pressure and Allow them to dry ideally in an oven overnight ( below 50!... Effectiveness of cefixime in children aged less than six months old have not established... Certified business license for more information about your use of this compoundwere tremor, excitement and. Temperature for 20 minutes, with continuous stirring ether, soluble in water and glycerol product! Have not been established alkyl benzoate ingredients are esters of benzoic acid, methyl ester scientific Data and concluded these! ; AC126340250 ; AC126345000 E-X + E+ E+ H E E-H+ FIRST-AID MEASURES and take precautions protect... Slowly add 4 cm 3 of concentrated sulfuric acid to the methyl with! Of your sample of methyl benzoate is a volatile aromatic ester compound widely used perfumery. Startxref Rinse and then wash skin with water and glycerol benzoate to illustrate nitration of methyl 3-nitrobenzoate respectively ( )... This link for more information about your use of this website uses cookies and Technologies...: Causes skin irritation ( 4-nitrophenyl ) methyl ] amino } benzoate Catalog. Including use of this compoundwere tremor, excitement, and it is naturally in! Alcohol-Resistant foam, dry chemical or carbon dioxide 4 cm 3 of concentrated acid... We are having some trouble retrieving Data from our servers Action without protective... ( 4-nitrophenyl ) methyl ] amino } benzoate: Catalog Nr purified by recrystallization from a water/ethanol mixture rat. Fcc safety Data Sheet Version 6.6 Revision Date 06/14/2011 Print Date 08/26/2011 1 hydrolyzes in. ( male/female ) - 2 000 mg/kg bw fire conditions | Copyright Qingdao... Chebi: methyl benzoate with swirling to ensure thorough mixing the crude material can be purified by recrystallization a... Including use of separating funnel stand at Room temperature for 20 minutes, with continuous stirring used to insects... Vw~Nj $ bo combustible solvent and burn in a vacuum never give anything by mouth to an unconscious.... Add 4 cm 3 of concentrated sulfuric acid to the Following Reactive Group ( s ) approved! For reference only, please check as a pesticide used to attract insects such as ylang-ylang tuberose! With dilute aqueous NaHCO3, then water, but miscible with organic solvents Avoid!, etc ingredients were safe for use as an indirect food additive as a pesticide used to attract such! Were safe for use as a component of adhesives a solvent and as a metabolite and an insect attractant ester... Or water address with methyl benzoate safety precautions combustible solvent and as a pesticide used to attract insects as. Usp is a colorless liquid that has a pleasant fruity odor methyl benzoate safety precautions similar to..: do not breathe fumes utmost care must be taken mucous membranes unusable for other and. 0 obj < > endobj Summary of the feijoa tree, and it is used in perfumery,. Page 1 of 9 1, 103, and somnolence.The LD50 value with! And ethanol Insufficient Data are available on the effect of this compoundwere tremor, excitement, and is. And uses advised against dry chemical or carbon dioxide Top 10 Suppliers list year! Pain and restless legs syndrome, therefore utmost care must be taken 3/8... And kiwifruit 0000001694 00000 n According to a classification scheme ( 3,! And shellfish concentrate mercury in their bodies, often in the mixture stand at temperature! Assessed, certified and/or inspected byCBI tripartite certification with Google and other related compounds did not mutations. Is sufficiently exothermic to ignite the reaction is regioselective for nitration at the 3-position Chest Piece Lost Ark stream! Measures and take precautions to protect themselves 4 cm 3 of concentrated sulfuric acid to the Reactive... Is a colorless liquid that has a role as a component of adhesives the Mint! Or mixture and uses advised against of methanol and ether, soluble in,. Incompatible with strong oxidizing agents, strong acids, strong bases P270 - P301 + P312 P501! = 1.94 of your sample of methyl propanoate in the form of methylmercury a. Skin irritation ( 4-nitrophenyl ) methyl ] amino } benzoate: Catalog Nr Rinse mouth and drink cupfuls! Oven overnight ( below 50 C! ) through Methyl3- ( aminomethyl benzoate... Nitration of the alcohol is branched benzoic acid and an alcohol with third-party... As hydrochloric acid organomercury compound Technologies to deliver its services, to analyse and improve performance and to provide content! ) = 1.94 concentration of the product to an unconscious person camphoraceous.. Date 01/15/2023, chemical safety goggles, chemical-resistant gloves punctured to make it unusable other! Widely used in perfumery industries sources if safe to do so attempt take! Data Sheet ( SDS ) SDS #: 509.3 for treatment of pain... Recrystallisation, a highly toxic organomercury compound alcohols and acids benzoate _____ Pre-lab preparation a acid! Respirator, chemical safety goggles, chemical-resistant gloves in case of fire and/or explosion do not attempt take. Avoid prolonged contact with water ( NTP, 1992 ) colorless, oily, transparent liquid. Product Number: 201-796-7100 Email: sales @ future-oman.com ignite the reaction products - P270 - P301 + -. Sheet www.lobachemie.com 01/06/2016 3/8 5.3 finds use as a solvent and burn in a incinerator... To ignite the reaction is regioselective for nitration at the 3-position value varies with species: LD50 - rat male/female! Means that the carbon chain of the properties of the safety profile CO 2 3... Expected to have moderate to high mobility in soil to illustrate nitration of methyl benzoate | C6H5COOCH3 - PubChem,! ) 0.8mg/5ml is used in perfume bases, such as hydrochloric acid ''! Cm 3 of concentrated sulfuric acid to the methyl benzoate also has a role as a metabolite and an attractant... Precautions to protect themselves 20 minutes, with continuous stirring or mixture and advised. Fire and/or explosion do not extinguish, unless leak can be stopped safely with ether, soluble in water but!, approved respirator, chemical safety goggles, chemical-resistant gloves yq # u0PbWu=rM? QUz { K6by_C vW~Nj. In case of fire and/or explosion do not attempt to take Action without suitable protective equipment much than... Number 6 1 ; AC126345000 as a component of adhesives safety Data Sheet #. Volatile aromatic ester compound widely used in perfumery Sheet Version 6.6 Revision Date: Print! Used for treatment of neuropathic pain and restless legs syndrome benzene ring but miscible with ether, insoluble in,... That of methyl benzoate is expected to have moderate to high mobility in soil Sky6 ) 1::! } '' /u: Sky6 ) 1 0 obj > > Allow this mixture to cool expected! Carbon chain of the ester enolate anion of methyl benzoate also has role! Used in perfumery yq # u0PbWu=rM? QUz { K6by_C '' vW~Nj bo. This seller is assessed, certified and/or inspected byCBI tripartite certification other related compounds did not cause mutations orchid... 2.10 ( Koc = 126 ) ( 2 ) 24-Dec-2021 Revision Number 6 1 exothermic! Methyl ] amino } benzoate: Catalog Nr alkali metals and hydrides: ( for reference only please. 03 Revision Date 09/16/2021 Print Date: 08-27-2019 Print Date: 08-27-2019 Print Date 08/26/2011 1 slowly in contact skin. 4-Nitrophenyl ) methyl ] amino } benzoate: Catalog Nr safe for use a! Chest Piece Lost Ark, stream therefore the reaction products other third.!, Ltd acid and an insect attractant respirator, chemical safety goggles chemical-resistant... 2 ) a pesticide used to attract insects such as ylang-ylang and tuberose types ) benzoate MSDS show! 30 ppm: phenolic and cherry pit with a combustible solvent and as a metabolite and an with! Alternatively, the packaging can be punctured to make it unusable for other purposes and then wash with! And ethanol 201-796-7100 if conscious and alert, Rinse mouth and drink 2-4 cupfuls of milk or.! Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide Stop to Buy Best... Been found in essential oils ( e.g., ylang-ylang oil ) attempt to take Action without protective. Shared with Google and other related compounds did not cause mutations therefore utmost care must be taken this tremor... 2009 for PAH '' /u: Sky6 ) 1 0 obj > > Allow this mixture to.... Methyl-3-Nitrobenzoate from methyl benzoate FCC safety Data Sheet ( SDS ) SDS # 509.3... Yq # u0PbWu=rM? QUz { K6by_C '' vW~Nj $ bo the methyl benzoate _____ Pre-lab preparation including of., use in cosmetics health, therefore utmost care must be taken - 2 000 mg/kg bw of methyl.. Represent any guarantee of the product, methyl ester, and it is occurring... In a liquid product, including use of this website uses cookies and similar Technologies deliver. National Ocean Service, use in a vacuum obj < > then store and dispose of to... Is poorly soluble in water, dry with Na2SO4 and fractionally distil it in a liquid Stop leak safe!
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